ThuliumV1, Main, Exploration, bibRecord, 003A20

Synthesis, crystal structure and magnetic properties of Tm8S11

Identifieur interne : 003A20 ( Main/Exploration ); précédent : 003A19; suivant : 003A21

Synthesis, crystal structure and magnetic properties of Tm8S11

Auteurs : Y. Zhang [États-Unis] ; H. F. Franzen [États-Unis] ; B. Harbrecht [Allemagne]

Source :

Journal of The Less-Common Metals [ 0022-5088 ] ; 1990.

RBID : ISTEX:EED8AC53FAAF0BD4B68DD5B8A35EEAED99BF5E95

Descripteurs français

Pascal (Inist)
- Composé minéral, Diffraction RX, Etude expérimentale, Structure cristalline, Susceptibilité magnétique, Synthèse, Thulium Sulfure.
Wicri :
- topic : Composé minéral.

English descriptors

KwdEn :
- Acta crystallogr, Ames, Ames laboratory, Cmcm, Crystal data, Crystalline structure, Experimental study, Inorganic compound, Magnetic susceptibilities, Magnetic susceptibility, Prism, Space group cmcm, Structure determination, Structure type, Sulfur atoms, Susceptibility, Synthesis, Temperature dependence, Thermal parameters, Thulium, Thulium Sulfides, Thulium atoms, Tmss, Trigonal prism, Trigonal prisms, Valence, X ray diffraction.
Teeft :
- Acta crystallogr, Ames, Ames laboratory, Cmcm, Crystal data, Magnetic susceptibilities, Prism, Space group cmcm, Structure determination, Structure type, Sulfur atoms, Susceptibility, Temperature dependence, Thermal parameters, Thulium, Thulium atoms, Tmss, Trigonal prism, Trigonal prisms, Valence.

Abstract

Abstract: The title compound was prepared by high temperature techniques. An X-ray diffraction study of a single crystal has identified a new structure type with composition Tm8S11, space group Cmcm; Z = 4;a = 3.7486(4), b = 12.6160(8), c = 34.932(3) Å. The coordination for Tm atoms is distorted octahedra, distorted trigonal prisms or capped trigonal prisms. These types of coordination are quite common for rare-earth chalcogenides. The magnetic susceptibility measurements show that all Tm atoms in Tm8S11 have a valence of +3 and there are eight delocalized electrons per cell.

Url:

https://api.istex.fr/document/EED8AC53FAAF0BD4B68DD5B8A35EEAED99BF5E95/fulltext/pdf

DOI: 10.1016/0022-5088(90)90373-R

Affiliations:

Le document en format XML

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<front><div type="abstract" xml:lang="en">Abstract: The title compound was prepared by high temperature techniques. An X-ray diffraction study of a single crystal has identified a new structure type with composition Tm8S11, space group Cmcm; Z = 4;a = 3.7486(4), b = 12.6160(8), c = 34.932(3) Å. The coordination for Tm atoms is distorted octahedra, distorted trigonal prisms or capped trigonal prisms. These types of coordination are quite common for rare-earth chalcogenides. The magnetic susceptibility measurements show that all Tm atoms in Tm8S11 have a valence of +3 and there are eight delocalized electrons per cell.</div>
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Synthesis, crystal structure and magnetic properties of Tm8S11

Synthesis, crystal structure and magnetic properties of Tm8S11

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

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